Where Does the Carbon in Diamonds Come From?
this week I found THIS ARTICLE on the Earth-logs blog. It is based on THIS PAPER. It was thought that the carbon came from subducted sedimentary rocks. Then we thought of the basalts in the oceanic crust. Their reaction with aqueous fluids results in carbonates.
Current research uses the isotopic chemistry of carbon and nitrogen in the diamonds and the tiny silicate minerals included in them. Most of these are garnets. From the studies the depth of formation can be indicated and this can help determine the carbon source.
And it seems that the oceanic basalts are the favoured source.
But VERY deep diamonds - formed below 660km - may be different. The isotopes suggest that the carbon source is within the mantle and ultimately the stellar dust that accreted to form the earth. But at that depth the carbon is incorporated in metals and carbides. The authors suggest that subducted slabs, reaching that depth, release watery fluids which mobilise the trapped carbon and allow the formation of diamond.
Diamond crystal containing a garnet and other inclusions (Credit: Stephen Richardson, University of Cape Town, South Africa) |
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